netstat -a
Active UNIX domain sockets (servers and established)
Proto RefCnt Flags       Type       State         I-Node Path
unix  4      [ ]         DGRAM                    60     /dev/log
unix  2      [ ACC ]     STREAM     LISTENING     215    /dev/gpmctl
unix  2      [ ACC ]     STREAM     LISTENING     535    /var/run/mysql/mysql.sock
unix  2      [ ]         DGRAM                    166
unix  2      [ ]         DGRAM                    63
cat /etc/postfix/master.cf
#
# Postfix master process configuration file.  For details on the format
# of the file, see the Postfix master(5) manual page.
#
# ==========================================================================
# service type  private unpriv  chroot  wakeup  maxproc command + args
#               (yes)   (yes)   (yes)   (never) (100)
# ==========================================================================
smtp      inet  n       -       n       -       -       smtpd
#submission inet n      -       n       -       -       smtpd
#       -o smtpd_etrn_restrictions=reject
#       -o smtpd_client_restrictions=permit_sasl_authenticated,reject
#smtps    inet  n       -       n       -       -       smtpd
#  -o smtpd_tls_wrappermode=yes -o smtpd_sasl_auth_enable=yes
#submission   inet    n       -       n       -       -       smtpd
#  -o smtpd_etrn_restrictions=reject
#  -o smtpd_enforce_tls=yes -o smtpd_sasl_auth_enable=yes
#628      inet  n       -       n       -       -       qmqpd
pickup    fifo  n       -       n       60      1       pickup
cleanup   unix  n       -       n       -       0       cleanup
qmgr      fifo  n       -       n       300     1       qmgr
#qmgr     fifo  n       -       n       300     1       oqmgr
tlsmgr    unix  -       -       n       1000?   1       tlsmgr
rewrite   unix  -       -       n       -       -       trivial-rewrite
bounce    unix  -       -       n       -       0       bounce
defer     unix  -       -       n       -       0       bounce
trace     unix  -       -       n       -       0       bounce
verify    unix  -       -       n       -       1       verify
flush     unix  n       -       n       1000?   0       flush
proxymap  unix  -       -       n       -       -       proxymap
smtp      unix  -       -       n       -       -       smtp
# When relaying mail as backup MX, disable fallback_relay to avoid MX loops
relay     unix  -       -       n       -       -       smtp
        -o fallback_relay=
#       -o smtp_helo_timeout=5 -o smtp_connect_timeout=5
showq     unix  n       -       n       -       -       showq
error     unix  -       -       n       -       -       error
discard   unix  -       -       n       -       -       discard
local     unix  -       n       n       -       -       local
virtual   unix  -       n       n       -       -       virtual
lmtp      unix  -       -       n       -       -       lmtp
anvil     unix  -       -       n       -       1       anvil
scache    unix  -       -       n       -       1       scache
#
# ====================================================================
# Interfaces to non-Postfix software. Be sure to examine the manual
# pages of the non-Postfix software to find out what options it wants.
#
# Many of the following services use the Postfix pipe(

 delivery
# agent.  See the pipe(

 man page for information about ${recipient}
# and other message envelope options.
# ====================================================================
#
# maildrop. See the Postfix MAILDROP_README file for details.
# Also specify in main.cf: maildrop_destination_recipient_limit=1
#
maildrop  unix  -       n       n       -       -       pipe
  flags=DRhu user=vmail argv=/usr/local/bin/maildrop -d ${recipient}
#
# The Cyrus deliver program has changed incompatibly, multiple times.
#
old-cyrus unix  -       n       n       -       -       pipe
  flags=R user=cyrus argv=/cyrus/bin/deliver -e -m ${extension} ${user}
# Cyrus 2.1.5 (Amos Gouaux)
# Also specify in main.cf: cyrus_destination_recipient_limit=1
cyrus     unix  -       n       n       -       -       pipe
  user=cyrus argv=/cyrus/bin/deliver -e -r ${sender} -m ${extension} ${user}
#
# See the Postfix UUCP_README file for configuration details.
#
uucp      unix  -       n       n       -       -       pipe
  flags=Fqhu user=uucp argv=uux -r -n -z -a$sender - $nexthop!rmail ($recipient)
#
# Other external delivery methods.
#
ifmail    unix  -       n       n       -       -       pipe
  flags=F user=ftn argv=/usr/lib/ifmail/ifmail -r $nexthop ($recipient)
bsmtp     unix  -       n       n       -       -       pipe
  flags=Fq. user=foo argv=/usr/local/sbin/bsmtp -f $sender $nexthop $recipient
Това беше съдържанието на master.cf
Грешките които дава заради това че не поддържа mysql бяха други, мисля че се справих с този проблем като четох из гуъгл.
Как мога оправя проблема с mysql? 
 mysql -h localhost -u postfix -p
Enter password:
Welcome to the MySQL monitor.  Commands end with ; or \g.
Your MySQL connection id is 5 to server version: 4.1.14
Type 'help;' or '\h' for help. Type '\c' to clear the buffer.
mysql> exit
Това така работи. Не съм променял нищо по настройките на постфикс освен най-необходимите неща - спрямо статията на Н. Антoнов.
Това е съдържанието на /etc/my.cnf
[client]
#password       = your_password
port            = 3306
socket          = /var/run/mysql/mysql.sock
# Here follows entries for some specific programs
# The MySQL server
[mysqld]
port            = 3306
socket          = /var/run/mysql/mysql.sock
skip-locking
key_buffer = 16K
max_allowed_packet = 1M
table_cache = 4
sort_buffer_size = 64K
read_buffer_size = 256K
read_rnd_buffer_size = 256K
net_buffer_length = 2K
thread_stack = 64K
# Don't listen on a TCP/IP port at all. This can be a security enhancement,
# if all processes that need to connect to mysqld run on the same host.
# All interaction with mysqld must be made via Unix sockets or named pipes.
# Note that using this option without enabling named pipes on Windows
# (using the "enable-named-pipe" option) will render mysqld useless!
#
#skip-networking
server-id       = 1
# Uncomment the following if you want to log updates
#log-bin
# Uncomment the following if you are NOT using BDB tables
#skip-bdb
[mysqldump]
quick
max_allowed_packet = 16M
[mysql]
no-auto-rehash
# Remove the next comment character if you are not familiar with SQL
#safe-updates
[isamchk]
key_buffer = 8M
sort_buffer_size = 8M
[myisamchk]
key_buffer = 8M
sort_buffer_size = 8M
[mysqlhotcopy]
interactive-timeout